Showing chemical card for 3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid (CFc000166231)

Record Information

Version

1.0

Creation Date

2022-08-28 10:25:12 UTC

Update Date

2022-09-13 23:59:18 UTC

Chemfont ID

CFc000166231

Molecule Identification

Common Name

Definition

3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid belongs to the class of organic compounds known as xanthophylls. These are carotenoids containing an oxygenated carotene backbone. Carotenes are characterized by the presence of two end-groups (mostly cyclohexene rings, but also cyclopentene rings or acyclic groups) linked by a long branched alkyl chain. Carotenes belonging form a subgroup of the carotenoids family. Xanthophylls arise by oxygenation of the carotene backbone. Based on a literature review very few articles have been published on 3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid.

Structure

MOL SDF PDB SMILES InChI

MOL for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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3D MOL for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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3D SDF for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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3D-SDF for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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PDB for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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3D PDB for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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SMILES for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

[H]/C(=C(/[H])\C(\[H])=C(/C)\C(\[H])=C(/[H])\C(\[H])=C(/C)\C(\[H])=C(/[H])C12OC1(C)CC(CC2(C)C)OC1OC(C(O)C(O)C1O)C(O)=O)/C(/[H])=C(\C)/C(/[H])=C(\[H])/C(/[H])=C(/C)C([H])=C([H])C1C(C)=CC(O)CC1(C)C

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INCHI for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

InChI=1S/C46H64O9/c1-29(17-13-19-31(3)21-22-36-33(5)25-34(47)26-43(36,6)7)15-11-12-16-30(2)18-14-20-32(4)23-24-46-44(8,9)27-35(28-45(46,10)55-46)53-42-39(50)37(48)38(49)40(54-42)41(51)52/h11-25,34-40,42,47-50H,26-28H2,1-10H3,(H,51,52)/b12-11+,17-13+,18-14+,22-21+,24-23+,29-15+,30-16+,31-19-,32-20+

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Structure for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

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3D Structure for CFc000166231 (3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid)

Synonyms

Value	Source
3,4,5-Trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylate	Generator

Chemical Formula

C₄₆H₆₄O₉

Average Molecular Weight

761.009

Monoisotopic Molecular Weight

760.455033641

IUPAC Name

3,4,5-trihydroxy-6-({6-[(1E,3E,5E,7E,9E,11E,13E,15Z,17E)-18-(4-hydroxy-2,6,6-trimethylcyclohex-2-en-1-yl)-3,7,12,16-tetramethyloctadeca-1,3,5,7,9,11,13,15,17-nonaen-1-yl]-1,5,5-trimethyl-7-oxabicyclo[4.1.0]heptan-3-yl}oxy)oxane-2-carboxylic acid

Traditional Name

CAS Registry Number

Not Available

SMILES

[H]/C(=C(/[H])\C(\[H])=C(/C)\C(\[H])=C(/[H])\C(\[H])=C(/C)\C(\[H])=C(/[H])C12OC1(C)CC(CC2(C)C)OC1OC(C(O)C(O)C1O)C(O)=O)/C(/[H])=C(\C)/C(/[H])=C(\[H])/C(/[H])=C(/C)C([H])=C([H])C1C(C)=CC(O)CC1(C)C

InChI Identifier

InChI=1S/C46H64O9/c1-29(17-13-19-31(3)21-22-36-33(5)25-34(47)26-43(36,6)7)15-11-12-16-30(2)18-14-20-32(4)23-24-46-44(8,9)27-35(28-45(46,10)55-46)53-42-39(50)37(48)38(49)40(54-42)41(51)52/h11-25,34-40,42,47-50H,26-28H2,1-10H3,(H,51,52)/b12-11+,17-13+,18-14+,22-21+,24-23+,29-15+,30-16+,31-19-,32-20+

InChI Key

ZXRCNJUFHKROPI-KFKHRJTASA-N

Chemical Taxonomy

Description

Belongs to the class of organic compounds known as xanthophylls. These are carotenoids containing an oxygenated carotene backbone. Carotenes are characterized by the presence of two end-groups (mostly cyclohexene rings, but also cyclopentene rings or acyclic groups) linked by a long branched alkyl chain. Carotenes belonging form a subgroup of the carotenoids family. Xanthophylls arise by oxygenation of the carotene backbone.

Kingdom

Organic compounds

Super Class

Lipids and lipid-like molecules

Class

Prenol lipids

Sub Class

Tetraterpenoids

Direct Parent

Xanthophylls

Alternative Parents

Terpene glycosides
O-glucuronides
O-glycosyl compounds
Beta hydroxy acids and derivatives
Oxepanes
Monosaccharides
Pyrans
Oxanes
Secondary alcohols
Polyols
Acetals
Monocarboxylic acids and derivatives
Epoxides
Dialkyl ethers
Carboxylic acids
Oxacyclic compounds
Hydrocarbon derivatives
Organic oxides
Carbonyl compounds

Substituents

Xanthophyll
Terpene glycoside
1-o-glucuronide
O-glucuronide
Glucuronic acid or derivatives
Glycosyl compound
O-glycosyl compound
Beta-hydroxy acid
Oxepane
Hydroxy acid
Monosaccharide
Oxane
Pyran
Secondary alcohol
Polyol
Carboxylic acid derivative
Carboxylic acid
Dialkyl ether
Oxirane
Ether
Acetal
Organoheterocyclic compound
Oxacycle
Monocarboxylic acid or derivatives
Organic oxide
Hydrocarbon derivative
Organooxygen compound
Alcohol
Carbonyl group
Organic oxygen compound
Aliphatic heteropolycyclic compound

Molecular Framework

Aliphatic heteropolycyclic compounds

External Descriptors

Not Available

Functional Ontology

Not Available

Not Available

Not Available

Not Available

Physical Properties

Predicted Properties

Property	Value	Source
Water Solubility	0.0013 g/L	ALOGPS
logP	6.97	ALOGPS
logP	6.55	ChemAxon
logS	-5.8	ALOGPS
pKa (Strongest Acidic)	3.61	ChemAxon
pKa (Strongest Basic)	-1.4	ChemAxon
Physiological Charge	-1	ChemAxon
Hydrogen Acceptor Count	9	ChemAxon
Hydrogen Donor Count	5	ChemAxon
Polar Surface Area	149.21 Å²	ChemAxon
Rotatable Bond Count	13	ChemAxon
Refractivity	226.03 m³·mol⁻¹	ChemAxon
Polarizability	90.44 Å³	ChemAxon
Number of Rings	4	ChemAxon
Bioavailability	No	ChemAxon
Rule of Five	No	ChemAxon
Ghose Filter	No	ChemAxon
Veber's Rule	No	ChemAxon
MDDR-like Rule	Yes	ChemAxon

External Links

HMDB ID

HMDB0185961

DrugBank ID

Not Available

Phenol Explorer Compound ID

Not Available

FooDB ID

Not Available

KNApSAcK ID

Not Available

Chemspider ID

Not Available

KEGG Compound ID

Not Available

BioCyc ID

Not Available

BiGG ID

Not Available

Wikipedia Link

Not Available

METLIN ID

Not Available

PubChem Compound

Not Available

PDB ID

Not Available

ChEBI ID

Not Available

Food Biomarker Ontology

Not Available

References

Synthesis Reference

Not Available